Auto Air Conditioning - Selecting the proper o-rings for auto A/C service - What's the difference in the colors of o-rings used for
auto A/C service? Do or-rings have to be green? Can I only use green o-rings for auto A/C systems using R-134a refrigerant? 

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You're correct! That's the right answer!
The Auto A/C Service Question was...
Black o-rings are for older A/C systems. I should only use
green o-rings for R-134a A/C systems.

Although today’s automotive A/C systems utilize several different colors of o-rings, it’s important to understand that the replacement o-ring may be a different color than the one originally used by the vehicle manufacturer. Also understand that even though the common replacement o-ring color is green, there are countless other replacement o-rings that are compatible with today’s A/C systems and are available in a variety of colors including black, purple and yellow to name a few.

But the straight truth about o-rings is that In recent years, they have become available in an assortment of different colors. It would be very convenient if the color represented the material, but it does not. Therefore, just because the factory o-ring is green and the replacement one is green does not necessarily mean that they are both of the same rubber compound nor that the replacement one is acceptable for use in your system.

Likewise, when servicing an auto A/C system, you may find that the original factory o-rings are purple, yellow or tan or one of several other different colors, and the replacement you have is green. It’s important to understand that the color of the o-ring does not matter. What does matter is if the replacement o-ring being installed is manufactured from the proper compound.

All the issues about colored o-rings became compounded when auto A/C systems had to be retrofitted (for use with R-134a refrigerant). Part of the recommended retrofit procedure was to change o-rings. That was because rubber compounds used for R-12 and mineral oil would not withstand the chemical mixture of R-134a and Ester or PAG oil, nor would they withstand the higher heat from higher operating pressures.

As we already stated, the color of the o-ring in no way implies (or confirms) what material the o-ring is made of. The only important issue (besides the right size) is that the o-rings you use are manufactured from the right material. Having said that, you would think it’s pretty simple, right? If all suppliers used the same o-ring material, then all o-rings would be compatible.

We’re sorry to advise you that this has never been the case. The issues of o-ring colors was further complicated during the rush to retrofit. The concept of ‘blue’ o-rings was introduced (although it’s never been determined why). What really happened was that, at the start of the major retrofit period, the original equipment manufacturers changed most of the o-ring seals on new vehicles to ‘green’. This became a (not official) standard as manufacturers changed most o-ring compounds to HNBR (Hydrogenated Nitrile Butadiene Rubber) for better resistance to heat. However, being as creative as some suppliers can be, they simply used older black o-rings that were actually ‘painted’ blue, just to try and confuse you. (It must have been to confuse you because there is absolutely no reason to paint an o-ring. None whatsoever!). In fact, if you find you have any of these ‘painted’ o-rings, they should be discarded. The peeling paint can only contaminate your A/C system.

Also understand that part of the problem with various colors of o-rings occurrs because vehicle manufacturers typically outsource complete A/C assemblies (or systems). The component manufacturer’s supplying the vehicle manufacture may use one color o-ring while the vehicle manufacturer assembles the rest of the system with another color o-ring. Therefore, complete service kits for some vehicles include a variety of different o-ring colors. However, keep in mind that the color really doesn’t matter. It’s the material used that counts.

So what o-ring material is acceptable? In order to provide the absolute best answer, each specific application would have to be tested. By that, we mean that each refrigerant and oil mix should be tested throughout the various heat ranges. However, we know that specific testing is not practical, therefore we will show you the guidelines you should follow when selecting replacement o-ring seals.

There are three generally acceptable o-ring materials for automotive A/C systems. They are Nitrile, HNBR (Hydrogenated Nitrile Butadiene Rubber) and Neoprene. Extensive testing has proven the HNBR provide the best seal across all R-134a refrigerant and oil mixes throughout all the temperature ranges. Typically, HNBR o-rings are referred to as the ‘high temperature’ o-ring for R-134a sysetms. Over time, they shrink and/or expand the least. In some applications, you may find Nitrile or Neoprene used on the low side of the system only, where components are not subject to higher operating pressures and temperatures.

Therefore, understanding that the color of the o-ring really doesn’t matter, you should always use HNBR o-rings for replacements. They can be used on both the high and low side of the system without fear of excessive shrinkage or swelling.

How can you tell what the o-ring material is? Without specific testing of each o-ring for the material, you really can not tell. You should make it a point to purchase o-rings from reputable suppliers and they (almost always) advise of the o-ring material. Keep in mind that o-rings are one of the lowest priced components of the A/C system, but it’s so important to use the right ones.

O-Ring Compatibility :
So that you best understand the major differences in o-ring materials and their compatibility, we have provided a table (below) that shows the various o-ring materials (Nitrile, HNBR and Neoprene) and their compatibility with various refrigerants and oils. Keep in mind that this chart makes no consideration for heat ranges. Tests have proven that HNBR is the best across all heat ranges; Nitrile is acceptable for lower (or mid) heat ranges. Neoprene is only acceptable for low temperature ranges. This chart in no way represents a warranty or guarantee of compatibility as only specific testing can provide absolute assurance. The chart should be used as a guideline.

Refrigerant / Oil Nitrile HNBR Neoprene
R-12 / Mineral Oil Good Good Good
R-134a / PAG Oil Good Good Fair
Freeze-12 / Mineral Oil Good Marginal Good
Freeze-12 / Polyol Ester Oil Poor Poor Marginal
Frig-C / Mineral Oil Marginal Poor Good
Frig-C / Polyol Ester Oil Good Marginal Good
Hot Shot / Mineral Oil Marginal Marginal Good
Testing :
For those interested, understand that there is one simple test that you can easily do to help confirm that your o-ring is acceptable for use in R-134a A/C sysetms. The only problem is that the test is a ‘destructive’ test. That means once the test is completed, you will not be able to use the o-ring as it will be ruined in the test. Nonetheless, this could prove helpful if you’re trying to determine the acceptability of some old o-rings in your inventory.

Here’s the test: Beilsteit Test of Rubber Materials for Chlorine : Understand that this test will not confirm which material your o-rings are made of. It will only tell you if the rubber material contains chlorine. We know that both Nitrile and HNBR do not include chlorine. Therefore, determining whether or not chlorine is present will confirm the o-rings acceptability for use with R-134a refrigerant.

CAUTIONS:
- Always wear safety glasses
- Work in a well ventilated area
- DO NOT breathe the fumes; fumes are toxic

Requirements :
- Safety Glasses
- Propane torch (or similar heat source)
- Pliers (preferably needle nose)
- Copper wire (bare) about .05” -.10” in thickness

Testing Procedure : Use the pliers to create a ‘hook’ on one end of the bare copper wire. -Heat the hooked end of the wire until it’s ‘red’ hot -Hook the ‘inside diameter’ of the o-ring being tested. The red hot copper hook should cause the o-ring to smoke. USE EXTREME CAUTION: DO NOT BREATHE FUMES. They are toxic. Remove the o-ring from the hook. -Place the hook back into the upper portion of the flame. Watch the color of the flame. If the flame turns green, the o-ring material contains chlorine, and therefore could not be Nitrile or HNBR and is not acceptable for use in R-134a systems. If the flame does NOT turn green, you really don’t know what the o-ring material is, but you do know that the material does not contain chlorine and should be acceptable for use in R-134a systems.

Overall, it’s important to understand that the color of the o-ring really has nothing to do with the material it’s made of or if it’s compatible with the refrigerant and oil mix in the A/C system. For best results, always use o-rings from suppliers that assure HNBR o-rings for high temperature auto A/C service.

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